Several factors (steric,electronic,orbital interactions,etc.) can affect the inversion barrier of an amine. In the given pairs,which data is correctly placed?

  • A
    Comparison of $N(CH_3)_3$ and $N(i-Pr)_2(CH_3)$ with $\Delta G^{\ddagger} = 7.9 \ kcal/mol$ and $0.2 \ kcal/mol$ respectively.
  • B
    Comparison of $N$-methylaziridine and $N$-methylpyrrolidine with $\Delta G^{\ddagger} = 20.5 \ kcal/mol$ and $7.0 \ kcal/mol$ respectively.
  • C
    Comparison of $N(CH_3)_3$ and $NCl_3$ with $\Delta G^{\ddagger} = 7.9 \ kcal/mol$ and $22.9 \ kcal/mol$ respectively.
  • D
    All of these

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How many metamers are possible for the molecular formula $C_4H_{11}N$?

Which of the following is expected to be the least basic?

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Consider the following:
Statement-$I$: In the nitration of aniline,a significant amount of $m$-nitroaniline is formed.
Statement-$II$: In the presence of a strongly acidic medium,aniline is protonated to form the anilinium ion,which is meta-directing.

In the given carbylamine reaction,the value of $x$ (moles of $KOH$ consumed) is:
$C_6H_5NH_2 + CHCl_3 + xKOH \rightarrow C_6H_5NC + 3KCl + 3H_2O$

When aniline is nitrated with nitrating mixture in ice-cold condition, the major product obtained is

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